Three Empirical Correlations Connecting Gaseous Cluster Energies and Solvation Energies of Alkali Metal and Halide Ions
نویسندگان
چکیده
منابع مشابه
Three empirical correlations connecting gaseous cluster energies and solvation energies of alkali metal and halide ions.
This paper gives two empirical correlations of formation Gibbs energies of gaseous clusters DeltaG(f)n as function of number of solvent molecules attached to the ion, n, and one correlation connecting the DeltaG(f)n for each individual cluster with the total DeltaG(o)hydr value. The experimental ratios of DeltaG(f)2/DeltaG(f)1 and DeltaG(f)3/DeltaG(f)1 for both alkali metal and halide ions are ...
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15 صفحه اولElectron binding energies of aqueous alkali and halide ions: EUV photoelectron spectroscopy of liquid solutions and combined ab initio and molecular dynamics calculations.
Photoelectron spectroscopy combined with the liquid microjet technique enables the direct probing of the electronic structure of aqueous solutions. We report measured and calculated lowest vertical electron binding energies of aqueous alkali cations and halide anions. In some cases, ejection from deeper electronic levels of the solute could be observed. Electron binding energies of a given aque...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2006
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.22.533